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QuPPe-PO Method for products of Plant Origin

QuPPe-PO is a method collection for the analysis of highly polar pesticides in food of plant origin and honey. It involves extraction with acidified methanol and LC-MS/MS measurement. Various LC-MS/MS options are available to chose depending on the scope of analytes to be covered.

 

Compounds covered by each method:

LC Methods

M1.1: Ethephon, HEPA, Glyphosate, AMPA, Glufosinate, MPPA, N-Acetylglufosinate

M1.2: Ethephon, HEPA ("nonregulated Metabolite of Ethephon"), Glyphosate, AMPA, N-acetyl-AMPA, Glufosinate, MPPA, N-Acetylglufosinate, Fosetyl-aluminium, Phosphonic acid

M1.3: Ethephon, HEPA, Glyphosate, N-Acetylglyphosate, AMPA, N-Acetyl-AMPA, Glufosinate, MPPA, N-Acetylglufosinate, Fosetyl-aluminium, Phosphonic acid, Maleic hydrazide, Perchlorate, Chlorate, Cyanuric acid ("nonregulated metabolite of Melamin, also originating from other sources, e.g. from Cyanamide fertilizers via Melamine"), Bialaphos, Desmethyl-Dimethoate

M1.4: Phosphonic acid, Chlorate, Perchlorate, (better performing for these 3 compounds than method 1.3), Bromide, Thiocyanate, Bromate ("may be formed during oxidative treatments of water, e.g. chlorinations, ozonations")

M1.5: Ethephon, HEPA, Glyphosate, N-Acetyl-Glyphosate, AMPA, N-Acetyl-AMPA, Glufosinate, MPPA, N-Acetyl-Glufosinate, Fosetyl-aluminium, Phosphonic acid, Perchlorate, Chlorate, Bialaphos, Bromide, Maleic hydrazide

M1.6a and M1.6b: Ethephon, HEPA, Glyphosate, N-Acetyl-Glyphosate, AMPA, N-Acetyl-AMPA, Glufosinate, MPPA, N-Acetyl-Glufosinate, Fosetyl-aluminium, Phosphonic acid, Perchlorate, Chlorate, Bromide, Trifluoroacetic acid

M1.7a and M1.7b: Phosphonic acid, Perchlorate, Chlorate, Bromide 

M1.8: Cyanuric acid, Perchlorate, Chlorate, Maleic hydrazide

M1.9: Ethephon, HEPA, Glyphosate, N-Acetyl-Glyphosate, AMPA, N-Acetyl-AMPA, Glufosinate, MPPA, N-Acetyl-Glufosinate, Fosetyl-aluminium, Phosphonic acid, Perchlorate, Chlorate, Bromide, Trifluoroacetic acid, Bialaphos

M1.10: Ethephon, HEPA, Glyphosate, N-Acetyl-Glyphosate, AMPA, N-Acetyl-AMPA, Glufosinate, MPPA, N-Acetyl-Glufosinate, Fosetyl-aluminium, Phosphonic acid, Perchlorate, Chlorate, Bromide, Trifluoroacetic acid, Cyanuric acid, Maleic hydrazide

M2: Fosetyl-Al, Maleic hydrazide, Perchlorate

M3: Amitrole, Chlormequat, Mepiquat, Difenzoquat, Daminozide, Trimesium, ETU, PTU, Cyromazine

M4.1:Paraquat, Diquat, Chlormequat, Mepiquat, Difenzoquat, Daminozide, N,N‑Dimethylhydrazine, Trimesium (Trimethylsulfonium cation), Cyromazine, Melamine ("nonregulated Metabolite of Cyromazine also originating from other sources, e.g. Cyanamide fertilizers"), Propamocarb, Nereistoxin. Also with limitations Morpholine, Diethanolamine and Triethanolamine (= wax additives present in extracts of wax-treated crops) as well as some Triazole Derivative Metabolites (TDMs): 1,2,4-Triazole (TRZ), Triazole-alanine (TA), Triazole-acetic acid (TAA), Triazole-lactic acid (TLA)

M4.2: Amitrole, Chlormequat, Mepiquat, Mepiquat-4-hydroxy (metabolite only regulated in food of animal origin), Daminozide, ETU, PTU, Cyromazine, Melamine ("nonregulated Metabolite of Cyromazine also originating from other sources, e.g. Cyanamide fertilizers"), Trimesium, Nereistoxin, Difenzoquat, Aminocyclopyrachlor, Chloridazon-desphenyl, Propamocarb, Propamocarb-N-desmethyl ("nonregulated Metabolite of Propamocarb"), Propamocarb-N-oxide ("nonregulated Metabolite of Propamocarb"), Nicotine, Matrine, Oxymatrine, Maleic hydrazide. Also with limitations Diquat and Paraquat as well as Morpholine, Diethanolamine and Triethanolamine (= wax additives present in extracts of wax-treated crops).

M5: Chlormequat, Mepiquat, Difenzoquat, ETU, PTU

M6: Kasugamycin, Streptomycin

M7: Morpholine, Diethanolamine, Triethanolamine (= wax additives present in extracts of wax-treated crops) 

M8: 1,2,4-Triazole (TRZ), Triazole-alanine (TA), Triazole-acetic acid (TAA), Triazole-lactic acid (TLA) (= Triazole Derivative Metabolites, TDMs) and 1,2,3-Triazole

M9: Difluoroacetic acid (DFA acid), Trifluoroacetic acid (TFA acid)

M10:Triazole-alanine (TA), Triazole-acetic acid (TAA), Triazole-lactic acid (TLA) (= Triazole Derivative Metabolites, TDMs) and 1,2,3-Triazole

 

IC Methods

M11: Ethephon, HEPA, Glyphosate, N-Acetyl-Glyphosate, AMPA, Glufosinate, MPPA, N-Acetyl-Glufosinate, Fosetyl-aluminium, Phosphonic acid, Perchlorate, Chlorate, Bromide, Trifluoroacetic acid, Cyanuric acid

 

Last update of method: 23.07.2021

 

Last modified 27-07-2021, 09:18:32

Published 03-05-2019, 05:50:14

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